Hydrochemical characterization and assessment of groundwater in the Bechar-Kenadsa Coal Basin (Southwestern Algeria)
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In arid and semi-arid zones, groundwater is indispensable but has become extremely limited due to climate change, salinization, overexploitation, and other anthropogenic factors. This study assessed the hydrogeochemistry and quality of groundwater in the Bechar-Kenadsa region of Southwestern Algeria. A total of 37 borehole water samples tapping the aquifer system were collected across the entire study area using a simple random sampling method. These samples were analyzed for physicochemical parameters, as well as major cations and anions, using standard analytical methods. Hydrogeochemical characteristics were assessed using various software tools, including QGIS for cartography, XLSTAT, and diagrams such as Piper, Gibbs, Gaillardet, and Schoeller-Berkaloff. The results showed that the pH ranges from 6.70 to 7.97, while water temperatures vary minimally between 24.5°C and 24.7°C. Electrical conductivity ranges between 1993 and 16990 μS/cm. Regarding major ions, Ca+2 ranges from 45 to 915 mg/L, Mg+2 from 72 to 645 mg/L, and combined sodium and potassium (Na+, K+) range between 190.2 and 2718 mg/L. For anions, chloride (Cl−) ranges from 300 to 4400 mg/L, sulfate (SO4−2) from 11 to 3200 mg/L, bicarbonate (HCO3−) from 64 to 308 mg/L, and nitrate (NO3−) from 2 to 332 mg/L. The groundwater from this aquifer is used exclusively for agricultural purposes. Overall, these waters are highly mineralized, of poor quality, and not potable. This degraded water quality is attributed to the regional paleogeographic setting of coal formations, the vulnerability of the aquifer, the dissolution of slag heaps, the excessive use of fertilizers, and urban wastewater discharges. Furthermore, effective groundwater protection will rely on wastewater treatment, reduced fertilizer application, the protection of wellhead capture zones, regular water quality monitoring, and sustainable resource management.
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