Assessment of Metalaxyl migration through vadose zone of alluvial sandy soil using column experiment and HYDRUS numerical modeling


Submitted: 19 January 2023
Accepted: 3 May 2023
Published: 27 September 2023
Abstract Views: 466
PDF: 278
Supplementary Material: 87
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Authors

  • Nilesh Kumar Meshram Department of Earth and Environmental Studies, National Institute of Technology Durgapur, Durgapur, West Bengal, India.
  • Kalyan Adhikari Department of Earth and Environmental Studies, National Institute of Technology Durgapur, Durgapur, West Bengal, India.
  • Rhitwik Chatterjee Department of Earth and Environmental Studies, National Institute of Technology Durgapur, Durgapur, West Bengal, India.

Contemporary research on pesticides/fungicides as potential sources of groundwater contamination, including their migration pathways, especially in the Western Bengal basin (WBB), is scarce. The present research intends to study the vulnerability of groundwater towards pollution from metalaxyl. Metalaxyl is a fungicide added anthropogenically to the sandy soil of WBB for the cultivation of crops like tomatoes, potatoes and mustard. The study explores the mechanics of metalaxyl adsorption in soil and its migration to the associated groundwater system. Chemical analyses show high concentrations of metalaxyl within groundwater (472.9 μg/L, maximum amount) from the study area (Nadia district of WBB). The groundwater ubiquity score of metalaxyl (4.6) depicts that it is very much prone to leach through the sandy soils of WBB to the underlying groundwater system. The results of column leaching experiments and their congruence to the findings of numerical modelling study using HYDRUS software confirm the fact. The adsorptive resilience of the studied soils towards metalaxyl is insignificant (soils of North Chandmari (S1) =0.1087 mg/g, Ghoragacha (S2) =0.21 mg/g, and Khaldarpara (S3) =1.771 mg/g). However, the presence of excess iron concentration may enhance the adsorptive capacity of the soil toward Metalaxyl, thereby limiting its migration toward the zone of saturation.


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